Cation distribution and Electrical/Dielectric features of Ru substituted CoNiCuZn spinel ferrite nanoparticles

Basit Öğe Kaydı
dc.authoridhttps://orcid.org/0000-0003-1651-3591
dc.authoridhttps://orcid.org/0000-0002-2579-1617
dc.contributor.authorAlmessiere, Munirah A.
dc.contributor.authorShirsath, S. E.
dc.contributor.authorBaykal, A.
dc.contributor.authorMihmanlı, Ahmet
dc.contributor.authorGondal, M. A.
dc.contributor.authorSlimani, Yassine
dc.date.accessioned2025-07-08T12:38:56Z
dc.date.available2025-07-08T12:38:56Z
dc.date.issued2025
dc.departmentDiş Hekimliği Fakültesi
dc.description.abstractIn this study, Co0.25Ni0.25Cu0.25Zn0.25RuxFe2-xO4 (Rux→Co0.25Ni0.25Cu0.25Zn0.25Fe2-xO4) (x ≤ 0.1) nanospinel ferrite (NSFs) were manufactured via sol-gel combustion route, with varying Ru content x ≤ 0.1. The cubic spinel structure was confirmed for all products by XRD analysis. The cubic morphology of the products was confirmed via SEM (Scanning Electron Microscopy), HR-TEM (High Resolution Transmission Electron Microscopy) and TEM (Transmission Electron Microscopy) analyses. The chemical composition of the product has been confirmed by EDX (Energy Dispersive X-ray) analysis. The cation distribution was analyzed using the Bertaut method by comparing observed and calculated intensity ratios of selected X-ray diffraction reflections. The ionic radii of tetrahedral (Td) A-site and octahedral (Oh) B-site cations, theoretical lattice constants, and oxygen positional parameters were determined. Results indicate that Ru substitution leads to a slight expansion in the B-site ionic radius and a subtle increase in the lattice constant, while the A-site configuration remains unaffected. The oxygen positional parameter showed minimal change, indicating structural stability. Additionally, dielectric properties were examined, revealing that the dielectric constant increases with Ru content and T, following MaxwellWagner interfacial polarization. AC conductivity analysis indicated thermally activated hopping mechanisms with enhanced polaron hopping due to Ru substitution. Dielectric measurements showed that the dielectric constant increased with Ru content, reaching a maximum of 150,000 at low frequencies for x = 0.10. AC conductivity analysis demonstrated thermally activated hopping mechanisms, with conductivity values increasing from 0.3 S/m for x = 0.00–1.2 S/m for x = 0.10 at 120 ◦C. This study presents insights into the structural and electrical features of Rux→Co0.25Ni0.25Cu0.25Zn0.25Fe2-xO4 (x ≤ 0.1) NSFs, which could be valuable for magnetooptical applications.
dc.identifier.doihttps://doi.org/10.1016/j.ceramint.2025.01.363
dc.identifier.endpage15282
dc.identifier.issn0272-8842
dc.identifier.issn1873-3956
dc.identifier.issue12
dc.identifier.scopusqualityQ1
dc.identifier.startpage15273
dc.identifier.urihttps://hdl.handle.net/11363/10063
dc.identifier.volume51
dc.indekslendigikaynakScopus
dc.institutionauthorMihmanlı, Ahmet
dc.language.isoen
dc.publisherElsevier Ltd
dc.relation.ispartofCeramics International
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAC conductivity
dc.subjectElectrical and dielectric properties
dc.subjectRare earth ion substitutions
dc.subjectSol-gel synthesis
dc.titleCation distribution and Electrical/Dielectric features of Ru substituted CoNiCuZn spinel ferrite nanoparticles
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
Makale / Article
Boyut:
10.27 MB
Biçim:
Adobe Portable Document Format
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
[ N/A ]
İsim:
license.txt
Boyut:
1.17 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

Web of Science ve Scopus Atıf Dizinlerindeki Yayınlar
Scopus İndeksli Yayınlar Koleksiyonu