Cyano-Bridged Trimetallic Coordination Polymer Nanoparticles and Their Thermal Decomposition into Nanoporous Spinel Ferromagnetic Oxides

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dc.authoridTOMINAKA, Satoshi/0000-0001-6474-8665
dc.authoridHu, Ming/0000-0002-5024-5650
dc.authoridBelik, Alexei/0000-0001-9031-2355
dc.authoridZakaria, Mohamed Barakat/0000-0003-2525-0092
dc.authoridHu, Ming/0000-0002-5024-5650
dc.authoridShiddiky, Muhammad J. A./0000-0003-4526-4109
dc.authoridKim, Jung Ho/0000-0003-4931-3553
dc.contributor.authorZakaria, Mohamed B.
dc.contributor.authorHossain, Md. Shahriar A.
dc.contributor.authorShiddiky, Muhammad J. A.
dc.contributor.authorShahabuddin, Mohammed
dc.contributor.authorYanmaz, Ekrem
dc.contributor.authorKim, Jung Ho
dc.contributor.authorBelik, Alexei A.
dc.date.accessioned2024-09-11T19:50:05Z
dc.date.available2024-09-11T19:50:05Z
dc.date.issued2016
dc.departmentİstanbul Gelişim Üniversitesien_US
dc.description.abstractThe synthesis of a novel family of cyano-bridged trimetallic coordination polymers (CPs) with various compositions and shapes has been reported by changing the compositional ratios of Fe, Co, and Ni species in the reaction system. In order to efficiently control the nucleation rate and the crystal growth, trisodium citrate dihydrate plays an important role as a chelating agent. After the obtained cyanobridged trimetallic CPs undergo thermal treatment in air at three different temperatures (250, 350, and 450 degrees C), nanoporous spinel metal oxides are successfully obtained. Interestingly, the obtained nanoporous metal oxides are composed of small crstalline grains, and the grains are oriented in the same direction, realizing pseudo-single crystals with nanopores. The resultant nanoporous spinel oxides feature interesting magnetic properties. Cyano-bridged multimetallic CPs with various sizes and shapes can provide a pathway toward functional nanoporous metal oxides that are not attainable from simple cyano-bridged CPs containing single metal ions.en_US
dc.description.sponsorshipCulture Affairs & Missions Sector of the Ministry of Higher Education in Egypt; Australian Institute for Innovative Materials (AIIM); University of Wollongong's Global Challenge Program; Deanship of Scientific Research at King Saud University through Research Group Project [RGP-290]en_US
dc.description.sponsorshipThe authors thank the Culture Affairs & Missions Sector of the Ministry of Higher Education in Egypt for financial support. This work was partially supported by the Australian Institute for Innovative Materials (AIIM) Gold/2015 grant and the University of Wollongong's Global Challenge Program/2015 grant. The authors would like to extend their sincere appreciation to the Deanship of Scientific Research at King Saud University for its funding of this research through the Research Group Project (RGP-290).en_US
dc.identifier.doi10.1002/chem.201603220
dc.identifier.endpage15048en_US
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.issue42en_US
dc.identifier.pmid27594526en_US
dc.identifier.scopus2-s2.0-84984873606en_US
dc.identifier.startpage15042en_US
dc.identifier.urihttps://doi.org/10.1002/chem.201603220
dc.identifier.urihttps://hdl.handle.net/11363/7553
dc.identifier.volume22en_US
dc.identifier.wosWOS:000384806700036en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistry-A European Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240903_Gen_US
dc.subjectcoodination polymersen_US
dc.subjectmagnetic propertiesen_US
dc.subjectmetal oxidesen_US
dc.subjectnanoporous materialsen_US
dc.titleCyano-Bridged Trimetallic Coordination Polymer Nanoparticles and Their Thermal Decomposition into Nanoporous Spinel Ferromagnetic Oxidesen_US
dc.typeArticleen_US

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