ZnO-loaded mesoporous silica (KIT-6) as an efficient solid catalyst for production of various substituted quinoxalines

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dc.authoridWu, Kevin/0000-0003-0590-1396
dc.authoridAlshehri, Saad/0000-0002-4990-6183
dc.authoridNguyen, Chi/0000-0001-7352-2342
dc.authoridYamauchi, Yusuke/0000-0001-7854-927X
dc.authoridHOSSAIN, MD Shahriar/0000-0002-7291-9281
dc.contributor.authorHamid, Oveisi
dc.contributor.authorChari, M. Adharvana
dc.contributor.authorChi Van Nguyen
dc.contributor.authorChen, Jeffrey E.
dc.contributor.authorAlshehri, Saad M.
dc.contributor.authorYanmaz, Ekrem
dc.contributor.authorHossain, Shahriar A.
dc.date.accessioned2024-09-11T19:50:49Z
dc.date.available2024-09-11T19:50:49Z
dc.date.issued2017
dc.departmentİstanbul Gelişim Üniversitesien_US
dc.description.abstractConventional homogeneous and microporous heterogeneous catalysts for quinoxalines production from diamines and diketones usually suffer from difficult separation or harsh reaction conditions. Here, we demonstrate the production of various substituted quinoxalines using ZnO nanoparticle-loaded, highly ordered, mesoporous silica KIT-6 materials as solid catalysts in room temperature. The results show that the KIT-6-130-10Zn sample (aged at 130 degrees C and containing 10 wt% ZnO) effectively produces quinoxalines up to the maximum of 99%. We propose that the enhanced performance of the ZnO-loaded KIT-6 materials resulted from the homogeneous distribution of ZnO nanoparticles, along with the KIT-6's high specific surface area and large pore sizes. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipMinistry of Science and Technology (MOST), Taiwan [104-2628-E-002-008-MY3]; National Taiwan University [105R7706]; Hakim Sabzervari Universality; AIIM (Australian Institute for Innovative Materials); International Scientific Partnership Program (ISPP) at King Saud University (KSU) [ISPP-0024]; University of Wollongong's Global Challenge Programen_US
dc.description.sponsorshipThe authors are grateful to the Director of Dr.MACS Bio-Pharma Pvt Ltd., for providing facilities. K.W. would like to thank the Ministry of Science and Technology (MOST), Taiwan (104-2628-E-002-008-MY3) and the National Taiwan University (105R7706) for the funding support. H.O. would like to thank the Hakim Sabzervari Universality for funding support. This work was partially supported by the AIIM (Australian Institute for Innovative Materials) for Gold/2014/2015 and University of Wollongong's Global Challenge Program/2015 grant. The authors extend their appreciation to the International Scientific Partnership Program (ISPP) at King Saud University (KSU) for funding this research work through ISPP-0024.en_US
dc.identifier.doi10.1016/j.catcom.2016.10.026
dc.identifier.endpage115en_US
dc.identifier.issn1566-7367
dc.identifier.issn1873-3905
dc.identifier.scopus2-s2.0-85007106953en_US
dc.identifier.startpage111en_US
dc.identifier.urihttps://doi.org/10.1016/j.catcom.2016.10.026
dc.identifier.urihttps://hdl.handle.net/11363/7678
dc.identifier.volume90en_US
dc.identifier.wosWOS:000392039000026en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofCatalysis Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240903_Gen_US
dc.subjectMesoporous materialsen_US
dc.subjectZnOen_US
dc.subjecto-Phenylenediamineen_US
dc.subject1,2-Diketonesen_US
dc.subjectQuinoxalinesen_US
dc.titleZnO-loaded mesoporous silica (KIT-6) as an efficient solid catalyst for production of various substituted quinoxalinesen_US
dc.typeArticleen_US

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