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Öğe Effect of nano-silica on the chemical durability and mechanical performance of fly ash based geopolymer concrete(ELSEVIER SCI LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND, 2018) Çevik, Abdulkadir; Alzeebaree, Radhwan; Humur, Ghassan; Niş, Anıl; Gülşan, Mehmet ErenIn this study, the effect of nano silica on the short term severe durability performance of fly ash based geopolymer concrete (GPC) specimens was investigated. Four types of GPC were produced with two types of low calcium fly ashes (FAI and FAII) with and without nano silica, and ordinary Portland cement concrete (OPC) concrete was also cast for reference. For the geopolymerization process, the alkaline activator has selected a mixture of sodium silicate solution (Na2SiO3) and sodium hydroxide solution (NaOH) with a ratio (Na2SiO3/ NaOH) of 2.5. Main objectives of the study were to investigate the effect of usability or replaceability of nano silica-based low calcium fly ash based geopolymer concretes instead of OPC concrete in structural applications and make a contribution to standardization process of the fly ash based geopolymer concrete. To achieve the goals, four types of geopolymer and OPC concretes were subjected to sulfuric acid (H2SO4), magnesium sulfate (MgSO4) and seawater (NaCl) solutions with concentrations of 5%, 5%, and 3.5%, respectively. Visual appearances and weight changes of the concretes under chemical environments were utilized for durability aspects. Compressive, splitting tensile and flexural strength tests were also performed on specimens to evaluate the mechanical performance under chemical environments. Results indicated that FAGPC concretes showed superior performance than OPC concrete under chemical attacks due to low calcium content. Amongst the chemical environments, sulfuric acid (H2SO4) was found to be the most dangerous environment for all concrete types. In addition, nano silica (NS) addition to FAGPC specimens improved both durability and residual mechanical strength due to the lower porosity and more dense structure. The FAIIGPC specimens including nano silica showed the superior mechanical performance under chemical environment.Öğe Effect of nano-silica on the chemical durability and mechanical performance of fly ash based geopolymer concrete (vol 44, pg 12253, 2018)(Elsevier Sci Ltd, 2019) Cevik, Abdulkadir; Alzeebaree, Radhwan; Humur, Ghassan; Nis, Anil; Gulsan, Mehmet Eren[Abstract Not Available]Öğe Mechanical and durability properties of fly ash and slag based geopolymer concrete(Techno-Press, 2018) Kurtoglu, Ahmet Emin; Alzeebaree, Radhwan; Aljumaili, Omar; Nis, Anil; Gulsan, Mehmet Eren; Humur, Ghassan; Cevik, AbdulkadirIn this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution (Na2SiO3) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid (H2SO4), magnesium sulfate (MgSO4) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid (H2SO4) was most dangerous environment for all concrete types.